Crooks, Gavin E. Nonequilibrium measurements of free energy differences for microscopically reversible Markovian systems. (English) Zbl 0946.82029 J. Stat. Phys. 90, No. 5-6, 1481-1487 (1998). Summary: An equality has recently been shown relating the free energy difference between two equilibrium ensembles of a system and an ensemble average of the work required to switch between these two configurations. In the present paper it is shown that this result can be derived under the assumption that the system’s dynamics is Markovian and microscopically reversible. Cited in 67 Documents MSC: 82C05 Classical dynamic and nonequilibrium statistical mechanics (general) Keywords:nonequilibrium statistical mechanics; free energy; work; thermodynamic integration; thermodynamic perturbation PDF BibTeX XML Cite \textit{G. E. Crooks}, J. Stat. Phys. 90, No. 5--6, 1481--1487 (1998; Zbl 0946.82029) Full Text: DOI OpenURL